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Jennifer Aniston Sparkles in Sexy Sequined Dress at Life of Crime L.A. Premiere: Picture

Jennifer Aniston at the Life of Crime Premiere
Jennifer Aniston sizzled on the red carpet at the Life of Crime premiere on Aug. 27

Whilst her ex-husband Brad Pitt and Angelina Jolie were off celebrating their Aug. 23 wedding, Jennifer Aniston was owning the red carpet for the premiere of her new film Life of Crime on Aug. 27 in Hollywood.

Related: PHOTOS: Jennifer's hot bikini bod

Aniston, engaged to Justin Theroux since 2012, sparkled in a Saint Laurent mini with a low-cut neckline. The Friends alum, 45, added a double-breasted blazer, ankle-strap heels and a black clutch to finish the ensemble.

Related: PHOTOS: Jennifer and Justin's love timeline

Her grown-out bob fell just below her shoulders, while the ageless beauty played up her eyes with bronze makeup and nude lips.

Related: PHOTOS: Hot celebs over 40 in swimsuits

Earlier in the day, Aniston made an appearance on Jimmy Kimmel Live, where she and her Friends costars Lisa Kudrow and Courteney Cox had a mini reunion.

Related: PHOTOS: Friends stars, then and now

The morning after Aniston sizzled on the red carpet, a spokesperson for Pitt and Jolie confirmed their surprise wedding, which took place on Saturday, Aug. 23, in France. The private ceremony was attended by close family and friends.

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